Bis[μ-methylenebis(diphenylphosphine)]bis[(5-nitro-1,10-phenanthroline)silver(I)] bis(hexafluoridoantimonate)
نویسنده
چکیده
In the title compound, [Ag(2)(C(12)H(7)N(3)O(2))(2)(C(25)H(22)P(2))(2)](SbF(6))(2), the two Ag(I) atoms are bridged by the two methyl-enebis(diphenyl-phosphine) ligands and an eight-membered centrosymmetric metallacyclic ring is formed. The metal atom exhibits a distorted tetra-hedral coordination geometry, coordinated by two P atoms of the bridging ligands and two N atoms of the chelating 5-nitro-1,10-phenanthroline ligand. The latter ligand shows minor disorder, adopting two orientations with site occupancy factors of 0.84 and 0.16.
منابع مشابه
Crystal structure of bis[μ-1,4-bis(diphenylphosphanyl)butane-κ2 P:P′]bis[(3,4,7,8-tetramethyl-1,10-phenanthroline-κ2 N,N′)copper(I)] bis(hexafluoridophosphate) dichloromethane disolvate
The dication of the title compound, [Cu2(C28H28P2)2(C16H16N2)2](PF6)2·2CH2Cl2, has crystallographically imposed inversion symmetry. The copper(I) cation is coordinated in a distorted tetra-hedral geometry by two N atoms of a chelating 3,4,7,8-tetra-methyl-1,10-phenanthroline ligand and two P atoms of two bridging 1,4-bis-(di-phenyl-phosphan-yl)butane ligands, forming a 14-membered ring. An intr...
متن کاملDi-μ-acetato-κ3 O,O′:O′;κ3 O:O,O′-bis[(acetato-κ2 O,O′)bis(5-nitro-1,10-phenanthroline-κ2 N,N′)cadmium]
In the binuclear title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(7)N(3)O(2))(2)], the Cd(II) cations are linked by carboxyl-ate O atoms into a four-membered Cd(2)O(2) rhombic ring with a Cd⋯ Cd separation of 3.7515 (5) Å. Each Cd(II) atom is seven-coordinated by a bidentate 5-nitro-1,10-phenanthroline (5-NO(2)-phen) ligand and two bidentate acetate anions, one of which also acts as a bridge link...
متن کاملBis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2 O 2:O 6)bis[bis(1,10-phenanthroline-κ2 N,N′)cobalt(II)] dimethylformamide disolvate
The asymmetric unit of the title compound, [Co(2)(C(10)H(2)O(4)S(3))(2)(C(12)H(8)N(2))(4)]·2C(3)H(7)NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octa-hedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2',3'-d]thio-phene-2,6-dicarb-oxy-l-ate...
متن کاملBis(μ-N-acetyl-N-phenylglycinato-κ2 O:O′)bis[dinitrato-κ4 O,O′-bis(1,10-phenanthroline-κ2 N,N′)lanthanum(III)]
In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenyl-glycinate ligands and four from two nitrate anions. Two La(III) cations, which exhibit a distorted bicapped square-anti-prismatic coordination, are bridged by two N-ace...
متن کاملBis(μ-2-phenoxypropionato-κ2 O:O′)bis[(1,10-phenanthroline-κ2 N,N′)bis(2-phenoxypropionato-κ2 O,O′)samarium(III)]
The dimeric title compound, [Sm(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], is centrosymmetric and is composed of six 2-phen-oxy-propionate anions and two 1,10-phenanthroline ligands. The Sm(III) atom is coordinated by two O atoms from two bridging anions, four O atoms from two chelating anions and the N atoms of the N-heterocycle in a distorted dodeca-hedral geometry.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007